Author, Subjects, Keywords

Cited Author

 

 
   » By Author or Editor
 » Browse Author by Alphabet
 » By Journal
 » By Subjects
 » Malaysian Journals
 » By Type
 » By Year
 » By Latest Additions
 
 
   » By Author
 » Top 20 Authors
 » Top 20 Article
 » Top Journal Cited
 » Top Article Cited
 » Journal Citation Statistics
 » Usage Since Sept 2007


 
 
 

Login | Create Account

La1-xSrxCo1-yFeyO3-d (LSCF) Composite as Durable Cathode Materials for Intermediate-Low Temperature Solid Oxide Fuel Cell: Research Review

Hamimah Abd.Rahman, and Muchtar, andanastuti, and Norhamidi Muhamad, and Huda Abdullah, (2010) La1-xSrxCo1-yFeyO3-d (LSCF) Composite as Durable Cathode Materials for Intermediate-Low Temperature Solid Oxide Fuel Cell: Research Review. Jurnal Kejuruteraan, 22 . pp. 1-10. ISSN 0128-0198

[img]
Preview
PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
906Kb

Official URL: http://www.ukm.my/jkukm/index.html

Affiliations

Universiti Kebangsaan Malaysia. Faculty of Engineering

Abstract

Solid oxide fuel cell (SOFC) is the most efficient fuel cell with the ability to directly convert chemical energy into electrical energy. Although there are numerous advantages offered by SOFCs, such as high energy conversion efficiency, low noise, less emission of pollutants and flexibility of hydrocarbon fuels, the processing cost and the performance improvement of SOFCs are hindered due to the higher operational temperatures. Therefore, the tendency to reduce the operational temperature of SOFC has brought about the development of research in materials and fabrication technology of fuel cells. Recently, among the many types of cathode materials that have been studied, lanthanum strontium cobalt ferrite, La 1-xSrxCo1-yFeyO3-d(LSCF) has been discovered to offer the most potential for use as cathode material in intermediate to low temperature SOFCs. The use of LSCF composite cathode has significantly reduced the cathode polarisation resistance and expanded the triple phase boundary (TPB) area available for oxygen reduction. The overall performance of cathodes and fuel cells are also influenced by the method of powder preparation and fabrication of the composite cathodes. As such, the present article focuses on the LSCF composites for use as durable cathode material in SOFCs from the aspects of materials development, powder preparation and fabrication techniques.

Item Type:Journal
Keywords:LSCF composite; cathode; intermediate-low temperature SOFC
Subjects:T Technology, Engineering
ID Code:11673

Asamoto, M., Miyake, S., Yonei, Y., Yamaura, H. & Yahiro, H. 2009. Electrochemical Performances of Proton-Conducting SOFC with La-Sr-Fe-O Cathode Fabricated by Electrophoretic Deposition Techniques. Electrochemistry 77 (2): 143-145.

Barqué, L., Canero, A., Moreno, M. S. & Serquis, A. 2008.

High performance nanostructured IT-SOFC cathodes prepared by novel chemical method. Electrochemistry Communications 10: 1905-1908.

Beckel, D., Dubach, A. & Studart, A. R. 2006. Spray pyrolisis of La0.6Sr0.4Co0.2Fe0.8O3-d thin film cathodes.

Journal of Electroceramics 16: 221-228.

Besra, L. & Liu, M. 2007. A review on fundamentals and

applications of electrophoretic deposition (EPD). Progress in Materials Science 52: 1-61.

Chen, F. & Liu, M. 2001. Preparation of yttria-stabilized

zirconia (YSZ) films on La0.85Sr0.15MnO3 (LSM)

and LSM-YSZ substrates using an electrophoretic

deposition (EPD) process. Journal of the European

Ceramic Society 21: 127-134.

Chen, J., Liang, F., Liu, L., Jiang, S., Chi, B., Pu, J. & Li, J. 2008. Nano-structured (La,Sr)(Co,Fe)O3 + YSZ

composite cathodes for intermediate temperature solid

oxide fuel cells. Journal of Power Sources 183: 586-589.

Cherng, J.S., Sau, J.R. & Chung, C.C. 2008. Aqueous

electrophoretic deposition of YSZ electrolyte layers

for solid oxide fuel cells. Journal of Solid State

Electrochemistry 12 (7-8): 925-933.

Dusastre, V. & Kilner, J. A. 1999. Optimisation of omposite

cathodes for intermediate SOFC applications. Solid State Ionics 126: 163-174.

Doshj, Richards, V.R., Carter, J., Wang, X. & Krumpelt

M. 1999. Development of solid-oxide fuel cells that operate at 500°C. Journal of Electrochemical Society 146: 1273-1278.

Fergus, J.W., Hui, R., Li, X., Wilkinson, D.P. & Zhang,

J. 2009. Solid Oxide Fuel Cells Materials Properties

and Performance. New York: CRC Press.

Fu, C., Sun, K., Zhang, N., Chen, X. & Zhou, D. 2007.

Electrochemical characteristics of LSCF-SDC composite cathode for intermediate temperature SOFC. Electrochimica Acta 52: 4589-4594.

Guo, W., Liu, J., Jin, C., Gao, H. & Zhang, Y. 2009.

Electrochemical evaluation of La0.6Sr0.4Co0.8Fe0.2O3-d-La0.9 Sr0.1Ga0.8Mg0.2O3-d composite cathodes for a0.9Sr0.1Ga0.8Mg 0.2O3-d electrolyte SOFCs. Journal of

Alloys and Compounds 473: 43-47.

Hagiwara, A., Hobara, N., Takizawa, K., Sato, K., Abe,

H. & Naito, M. 2006. Preparation and evaluation of mechanochemically fabricated LSM/ScSZ composite

materials for SOFC cathodes. Solid State Ionics 177: 2967-2977.

Lee, S., Song, H. S., Hyun, S. H., Kim, J. & Moon, J. 2009.

Interlayer-free nanostructured La0.58Sr0.4Co0.2Fe0.8O3-d

cathode on scandium stabilized zirconia electrolyte for intermediate-temperature solid oxide fuel cells. Journal of Power Sources 187: 74-79.

Lee, S., Song, H.S., Hyun, S.H., Kim, J. & Moon, J. 2010.

LSCF-SDC core-shell high-performance durable composite cathode. Journal of Power Sources 195: 118-123.8

Leng, Y.J., Chan, S.H., Jiang, S.P. & Khor, K.A.

2004. Low-temperature SOFC with thin film GDC electrolyte prepared in situ by solid-state reaction. Solid State Ionics 170: 9-15.

Leng, Y., Chan, S.H. & Liu Q. 2008. Development of LSCF-GDC composite cathodes for low-temperature solid oxide fuel cells with thin film GDC electrolyte. International Journal of Hydrogen Energy 33: 3808-3817.

Lin, Y. & Barnett, S.A. 2008. La0.8Sr0.1Ga0.8Mg0.2O3 - La0.6Sr0.4Co0.2Fe0.8O3-d composite cathodes for

intermediate-temperature solid oxide fuel cells. Solid

State Ionics 179: 420-427.

Liu, B. & Zhang, Y. 2008. Status and prospects of

intermediate temperature solid oxide fuel cells. Materials 15: 84-90.

Mathews, T., Rabu, N., Sellar, J.R. & Muddle, B.C. 2000.

Fabrication of La1-xSrxGa1-yMgyO3-(x+y)/2 thin films by electrophoretic deposition and its conductivity measurement. Solid State Ionics 128: 111-115.

Minh, N. Q. 2004. Solid oxide fuel cells technologyfeatures and application. Solid State Ionics 174: 271-277.

Murray, E.P., Sever, M.J. & Barnett, S.A. 2002.

Electrochemical performance of (La,Sr)(Co,Fe)O3-(Ce,Gd)O3

composites cathode. Solid State Ionics 148: 27-34.

Negishi, H., Sakai, N., Yamaji, K., Horita T. & Yokokawa,

H. 2000. Application of electrophoretic deposition technique to solid oxide fuel cells. Journal of

Electrochemical Society 147: 1682-1687.

NoorAshrina A. Hamid, Andanastuti Muchtar, Wan Ramli

Wan Daud & Norhamidi Muhamad. 2009. Pencirian mikrostruktur katod La-Sr-Co-Fe-O bagi Sel Fuel Oksida Pejal Bersuhu Sederhana (IT-SOFC). Sains Malaysiana 38(6).

Raj, I.A., Nesaraj, A.S., Kumar, M., Tietz, F., Buchkremer, H.P. & Stoever, D. 2004. On the suitability of La0.6.Sr0.4Co0.2Fe0.8O3-d cathode for intermediate

temperature solid oxide fuel cell (ITSOFC). Journal

of New Materials for Electrochemistry Systems 7: 145-151.

Ralph, J.M., Schoeler, A.C. & Krumpelt, M. 2001. Materials for lower temperature solid oxide fuel cells.

Journal of Materials Science 36: 1161-1172.

Riess, I. 2003. Mixed ionic-electronic conductors-materials

properties and applications. Solid State Ionics 157:

1-17.

Santillán, M.J., Caneiro, A., Quaranta, N. & Boccaccini,

A.R. 2009. Electrophoretic deposition of La0.6.Sr0.4Co0.2Fe0.8O3-d cathodes on Ce0.9Gd0.1O1.95

substrates for intermediate temperature solid oxide fuel cell (IT-SOFC). Journal of the European Ceramic Society 29: 1125-1132.

Serra, J. M, Uhlenbruck, S., Meulenberg, W. A., Buchkremer, H.P. & Stöver, D. 2006. Nano-structuring of solid oxide fuel cells cathodes. Topics in Catalysis. 40: 123-131.

Shao, Z. & Haile, S.M. 2004. A high-performance cathode

for the next generation of solid oxide fuel cells. Nature 431: 170-173.

Simner, S.P., Anderson, M.D., Templeton, J.W. &

Stevenson, J.W. 2007. Silver-perovskite composite SOFC cathodes processed via mechanofusion. Journal of Power Sources 168: 236-239.

Simner, S.P., Bonnett, J.F., Canfield, K.D., Meinhardt,

K.D., Shelton, J.P., Sprenkle, V.L. & Stevenson J.W. 2003. Development of lanthanum ferrite SOFC cathodes. Journal of Power Sources 113: 1-10.

Singhal, S.C. 2009. Solid Oxide Fuel Cell. http://

electrochem.cwru.edu/ed/encycl/ [30 Januari 2009].

Steven, S.C.C. 2005. Catalysis of Solid Oxide Fuel Cells.

Catalysis 18: 186-198.

Song, H.S., Kim, W.H., Hyun, S.H. & Moon, J. 2006a.

Influences of starting particulate materials on

microstructural evolution and electrochemical activity

of LSM-YSZ composite cathode for SOFC. Journal of Electroceramics 17: 759-764.

Song, L., Xueli, S., Zhongsheng, W. & Juncai, S. 2006b. A

new candidate as the cathode material for intermediate

and low temperature SOFCs. Rare Metals 25: 213-217.

Sora, I.N., Pelosato, R., Simone, A., Montanaro, L., Maglia, F. & Chiodelli, G. 2006. Characterization of

LSGM films obtained by electrophoretic deposition (EPD). Solid State Ionics 177: 1985-1989.

Tao, Y., Nishino, H., Ashidate, S., Kokubo, H., Watanabe,

M. & Uchida, M. 2009. Polarization properties of

La0.6Sr0.4Co0.2Fe0.8O3–d-based double layer-type oxygen

electrodes for reversible SOFCs. Electrochimica Acta 54: 3309-3315.

Thydén, K. 2008. Microstructural degradation of NiYSZ anodes for solid oxide fuel cells. Tesis Ph.D. University of Copenhagen, Denmark.

Viswanathan, B. & Scibioh, M. A. 2007. Fuel Cells

Principles and Applications. India: Universities Press,

CRC Press.

Wang, W. G. & Mogensen, M. 2005. High-performance

lanthanum-ferrite-based cathode for SOFC. Solid State Ionics 176: 457-462.

Wang, Z., Qian, J., Cao. J., Wang, S. & Wen, T. J. 2007.

A study of multilayer tape casting method for anodesupported planar type solid oxide fuel cells (SOFCs).

Journal of Alloys Compounds 437: 264-268.

Wincewicz, K. C. & Cooper, J. S. 2005. Taxonomies of

SOFC Material and Manufacturing Alternatives. Journal of Power Sources 140: 280-296.

Xia, C. & Liu, M. 2002. Novel cathodes for low temperature

solid oxide fuel cells. Advanced Materials 14: 521-523.

Yamamoto, O. 2000. Solid oxide fuel cells: fundamental

aspects and prospects. Electrochemica Acta 45: 2423-2435.

Yaseen, H., Baltianski, S. & Tsur. Y. 2007. Cathodic

electrophoretic deposition of barium titanate films from aqueous solution. Journal of Materials Science 942: 9676-9683.

Zhang, J., Ji, Y., Gao, H., He, T. & Liu, J. 2009. Composite cathode La0.6Sr0.4Co0.2Fe0.8O3–dSm0.1Ce0.9O1.95–Ag for intermediate-temperature solid oxide fuel cells.

Journal of Alloys and Compounds 395: 322-325.

Zhao, J., Wang, X. & Li, L. 2006. Electrophoretic deposition of BaTiO3 films from aqueous suspensions. Materials Chemistry and Physics 99: 350-353.

Repository Staff Only: item control page