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Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal

Saifuddin M. Nomanbhay, and Kumaran Palanisamy, (2008) Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal. Electronic Journal of Biotechnology, 8 (1). ISSN 07173458

Full text not available from this repository.

Official URL: http://www.ejbiotechnology.info/content/vol8/issue1/full/7/7.pdf

Affiliations

Universiti of Tenaga Nasional, College of Engineering
Universiti of Tenaga Nasional, College of Engineering

Abstract

This research focuses on understanding biosorption process and developing a cost effective technology for treatment of heavy metals-contaminated industrial wastewater. A new composite biosorbent has been prepared by coating chitosan onto acid treated oil palm shell charcoal (AOPSC). Chitosan loading on the AOPSC support is about 21% by weight. The shape of the adsorbent is nearly spherical with particle diameter ranging 100~150 μm. The adsorption capacity of the
composite biosorbent was evaluated by measuring the extent of adsorption of chromium metal ions from water under equilibrium conditions at 25ºC. Using Langmuir isotherm model, the equilibrium data yielded the following ultimate capacity values for the coated biosorbent on a per gram basis of chitosan: 154 mg Cr/g. Bioconversion of Cr (VI) to Cr (III) by chitosan was also observed and had been shown previously in other studies using plant tissues and mineral surfaces. After the biosorbent was saturated with the metal ions, the adsorbent was regenerated with 0.1 M sodium
hydroxide. Maximum desorption of the metal takes place within 5 bed volumes while complete desorption occurs within 10 bed volumes. Details of preparation of the biosorbent, characterization, and adsorption studies are presented. Dominant sorption mechanisms are ionic interactions and complexation.

Item Type:Journal
Keywords:Chitosan bioabsorbent, chromium (III), chromium (IV), heavy metal adsorption, oil palm shell charcoal
Subjects:S Agriculture
Q Science
ID Code:1890

AKSU, Z. Equilibrium and kinetic modeling of cadmium(II) biosorption by C. vulgaris in a batch system: effect of temperature. Separation and Purification Technology, 2001, vol. 21, p. 285-294.

BABEL, S. and KURNIAWAN, T.A. Cr (VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agent and/or chitosan. Chemosphere, February 2004, vol. 54, no.

7, p. 951-967.

BAILEY, S.E.; OLIN, T.J.; BRICKA, R.M. and ADRIAN, D.D. A review of potentially low costs sorbents for heavy metals. Water Research, 1999, vol. 33, no. 11, p. 2469-2479.

BAILEY, S.E.; OLIN, T.J. and BRICKA, R.M. Low-Cost Sorbents: Literature Summary. Technical Report SERDP-97-1, U.S. Army Engineer Waterways Experiment Station, Vicksburg, MS. 1997.

BENITO, Y. and RUIZ, M.L. Reverse osmosis applied to metal finishing wastewater. Desalination, 2002, vol. 142,no. 3, p. 229-234.

CADDICK, S. Microwave-assisted organic reactions. Tetrahedron, 1995, vol. 51, no. 38, p. 10403-10432.

CHAKRAVARTY, S.; DUREJA, V.; BHATTACHARYYA, G.; MAITY, S. and BHATTACHARJEE, S. Removal of arsenic from groundwater using low cost ferruginous manganese ore. Water Research, 2002; no. 36, vol. 3, p. 625-632.

CHAN, K.W. Biomass production in the oil palm industry. In: SINGH, G. et. al. eds. Oil palm and the environment: A Malaysian perspective. Malaysian Oil Palm Growers’ Council, Kuala Lumpur, 1999, p. 41-53.

CHEN, J.P. and CHANG, K.C. Immobilization of chitinase on a reversibly soluble-insoluble polymer for chitin hydrolysis. Journal of Chemical Technology and Biotechnology, June 1994, vol. 60, no. 2, p. 133-140.

CLESCERI, L.S.; GREENBERG, A.E. and EATON, A.D. Standard methods for the examination of water and wastewater. 20th ed. American Public Health Association, Washington, 1998; 1325 p. ISBN 0875532357.

COUGHLIN, R.W.; DESHAIES, M.R. and DAVIS, E.M. Preparation of chitosan for heavy metal removal. Environmental Progress, 1990, vol. 9, p. 35.

DAMBIES, L.; GUIMON, C.; YIACOUMI, S. and GUIBAL, E. Characterization of metal ion interactions with chitosan by X-ray photoelectron spectroscopy. Colloids and Surfaces, 2001, A., vol. 177, p. 203-214.

DEANS, J.R. and DIXON, B.G. Uptake of Pb2+ and Cu2+ by novel biopolymers. Water Research, 1992, vol. 26, no. 4, p. 469-472.

DESHPANDE, M.V. Enzymatic degradation of chitin and its biological applications. Journal of Scientific and Industrial Research, Sci. Ind. Res.,1986, vol. 45, p. 277-281.

FARIA, P.C.C.; ORFAO, J.J.M. and PEREIRA, M.F.R. Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Research, April 2004, vol. 38, no. 8, p. 2043-2052.

FU, M.; TANG, L.; ZHANG, P. and SHEN, D. Study on adsorption mechanism of Cr (VI) by CHT. Gongcheng Kexueban, (Journal of Sichuan Union University), 1997, vol. 1, 1997, p. 8-13.

GOTOH, T.; MATSUSHIMA, K and KIKUCHI, K.I. Preparation of alginate-chitosan hybrid gel beads and adsorption of divalent metal ions. Chemosphere, April 2004, vol. 55, no. 1, p. 135-140.

GUO, J. and LUA, A.C. Preparation and characterization of adsorbents from oil palm fruit solid waste. Journal of Oil Palm Research Malaysian Palm Oil Board, 2000, vol. 12,

p. 64-70.

GUO, J. and LUA, A.C. Characterization of chars pyrolyzed from oil palm stones for preparation of activated carbons. Journal of Analytical and Applied Pyrolysis, 1998, vol. 46, no. 2, p. 113.

HUSSEIN, M.Z.; TARMIZI, R.S.H.; ZAINAL, Z.; IBRAHIM, R. and BADRI, R.M. Preparation and characterization of active carbons from oil palm shells. Carbon, 1996, vol. 34, no. 11, p. 1447-1453.

ILYINA, A.V.; TIKHONOV, V.E.; VARLAMOV, V.P.; RADIGINA, L.A.; TATARINOVA, N.Y. and YAMSKOV, I.A. Preparation of affinity sorbents and isolation of individual chitinases from a crude supernatant produced by Streptomyces kurssanovii by a one-step affinity chromatographic system. Biotechnology and Applied Biochemistry, April 1995, vol. 21, no. 2, p. 139-148.

KADIRVELU, K.; THAMARAISELVI, K. and NAMASIVAYAM, C. Adsorption of nickel (II) from aqueous solution onto activated carbon prepared from coirpith. Separation and Purification Technology, 2001, vol. 24, p. 497-505.

KHMELNITSKY, Y.L. and RICH, J.O. Biocatalysis in non aqueous solvents. Current Opinion in Chemical Biology, 1999, vol. 3, p. 47-53.

KORTENKAMP, A.; CASADEVALL, M.; FAUX, S.P.; JENNER, A.; SHAYER, R.O.J.; WOODBRIDGE, N. and O’BRIEN, P. A role for molecular oxygen in the formation of DNA damage during the reduction of the carcinogen chromium (VI) by glutathione, Archives of Biochemistry and Biophysics, 1996, vol. 329, no. 2, p. 199-208.

LEON Y LEON, C.A.; SOLAR, J.M.; CALEMMA, V. and RADOVIC, L.R. Evidence for the protonation of basal plane sites on carbon. Carbon, 1992, vol. 30, no. 5, p. 789-811.

LYTLE, C.M.; LYTLE, F.W.; YANG, N.; QIAN, J.H.; HANSEN, D.; ZAYED, A. and TERRY, N. Reduction of Cr (VI) to Cr (III) by wetland plants: Potential for in situ heavy metal detoxification. Environmental Science and Technology, 1998, vol. 32, p. 3087-3093.

MENENDEZ, J.A.; PHILLIPS, J.; XIA, B. and RADOVIC, L.R. On the modification and characterization of chemical surface properties of activated carbon: in the search of carbons with stable basic properties. Langmuir, 1996, vol. 12, no. 18, p. 4404–4410.

MODAK, J.M. and NATARAJAN, K.A. Biosorption of metals using nonliving biomass: A review. Mineral Metallurgical Process, 1995; vol. 12, no. 4, p. 189-196.

MONSER, L., and ADHOUM, N. Modified activated carbon for the removal of copper, zinc, chromium, and cyanide from wastewater. Separation and Purification Technology, 2002, vol. 26, no. 2-3, p. 137-146.

MOSTAFA, M.R. Adsorption of mercury, lead and cadmium ions on modified activated carbon. Adsorption Science and Technology, 1997, vol. 15, no. 8, p. 551-557.

NORMAH, M.; TEO, K.C. and WATKINSON, A.P. Preparation and characterization of activated carbon derived from oil palm shells using a fixed bed pyrolyser. In: HASHIM, M.A. ed. Bioproducts Processing: Technologies for the tropics. Institute of Chemical Engineers, Rugby, United Kingdom, 1995, p. 93.

OLIN, T.J.; ROSADO, J.M.; BAILEY, S.E. and BRICKA, R.M. Low cost sorbents screening and engineering analysis of zeolite for treatment of metals contaminated water and soil extracts – final report. Report SERDP, 1996; 96-387, prepared for USEPA and SERDP.

OUKI, S.K.; NEUFELD, R.D. and PERRY, R. Use of activated carbon for the recovery of chromium from industrial wastewaters. Journal of Chemical Technology and Biotechnology, 1997, vol. 70, no. 1, p. 3-8.

PARK, S. and JUNG, W.Y. Removal of chromium by activated carbon fibers plated with copper metal. Carbon Scence, 2001, vol. 2, no. 1, p. 15-21.

RADOVIC L.R.; SILVA, I.F.; UME, J.I.; MENENDEZ, J.A.; LEON Y LEON, C.A. and SCARONI, A.W. An experimental and theoretical study of the adsorption of aromatics possessing electron-withdrawing and electrondonating functional groups by chemically modified activated carbons. Carbon, 1997, vol. 35, no. 9, p. 1339-1348.

RAJI, C. and ANIRUDHAN, T.S. Chromium (VI) adsorption by sawdust: kinetics and equilibrium. Indian Journal of Chemical Technology, 1997, vol. 4, no. 5, p.228-236.

RAMOS, R.L.; RANGEL-MENDEZ, J.R.; MENDOZABARRON, J.; FUENTES-RUBIO, L. and GUERREROCORONADO, R.M. Adsorption of cadmium (II) from aqueous solution onto activated carbon. Water Science Technology, 1997, vol. 30, p. 191-197.

RENGARAJ, S.; YEON, K.H. and MOON, S.H. Removal of chromium from water and wastewater by ion exchange resins. Journal of Hazardous Materials, October 2001, vol.87, no. 1-3, p.

273-287.

RODRIGUEZ-REINOSO, F. The role of carbon materials in heterogeneous catalysis. Carbon, 1998, vol. 36, no. 3, p.159-175.

ROY, I.; SARDAR, M. and GUPTA, M.N. Hydrolysis of chitin by PectinexTM. Enzyme and Microbial Technology, 2003, vol. 32, no. 5, p. 582-588.

SCHMUHL, R.; KRIEG, H.M. and KEIZER, K. Adsorption of Cu (II) and Cr (VI) ions by chitosan: Kinetics and equilibrium studies. Water S.A., 2001; vol. 27, no. 1, p. 1-8.

SHIM, J.W.; PARK, S.J. and RYU, S.K. Effect of modification with HNO3 and NaOH by pitch-based activated carbon fibers. Carbon, 2001; vol. 39, no. 11, p.SRIDAR, V. Microwave radiation as a catalyst for chemical reactions. Current Science, 1998, vol. 74, no. 5, p.446-450.

TAN, W.T.; OOI, S.T. and LEE, C.K. Removal of chromium (VI) from solution by coconut husk and palm pressed fibers. Environmental Technology, March 1993, vol. 14, no. 3, p. 277-282.

TIEMANN, K.J.; GARDEA-TORRESDEY, J.L.; GAMEZ, G.; DOKKEN, K and SIAS, S. Use of X-ray absorption and esterification to investigate Cr (III) and Ni (II) ligands in Alfafa biomass. Environmental Science and Technology, 1999, vol. 33, no. 1, p. 150-155.

TOLES, C.A.; MARSHALL, W.E. and JOHNS, M.M. Surface functional groups on acid activated nutshell carbons. Carbon, January 1999, vol. 37, no. 8, p. 1207-1214.

UDAYBHASKAR, P.; IYENGAR, L. and PRABHAKARA, R.A.V.S. Hexavalent chromium interaction with chitosan. Journal of Applied Polymer Science, February 1990, vol. 39, no. 3, p. 39-747.

VEGLIO, F. and BEOLCHINI, F. Removal of heavy metals by biosorption: A review. Hydrometallurgy, 1997, vol. 44, no. 3, p. 301-316.

WITTBRODT, P.R. and PALMER, C.D. Effect of temperature, ionic strength, background electrolytes and Fe (III) on the reduction of hexavalent chromium by soil humic substances. Environmental Science and Technology, 1996, vol. 30, no. 8, p. 2470-2477.

YANG, T.C. and ZALL, R.R. Adsorption of metals by natural polymers generated from sea food processing wastes. Industrial and Engeneering Chemistry Produc Research and Developmet, 1984, vol. 23, p. 168-172.

YURLOVA, L.; KRYVORUCHKO, A. and KORNILOVICH, B. Removal of Ni (II) ions from wastewater by micellar-enhanced ultrafiltration. Desalination, 2002, vol. 144, no. 255-260.

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