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High performance enzymatic synthesis of oleyl oleate using immobilised lipase from Candida antartica

Salina Mat Radzi, and Mahiran Basri, and Abu Bakar Salleh, and Arbakariya Ariff, and Rosfarizan Mohammad, and Mohd. Basyaruddin Abdul Rahman, and Raja Noor Zaliha Raja Abdul Rahman, (2005) High performance enzymatic synthesis of oleyl oleate using immobilised lipase from Candida antartica. Electronic Journal of Biotechnology, 8 (3). ISSN 07173458

Full text not available from this repository.

Official URL: http://www.ejbiotechnology.info/content/vol8/issue3/full/4/index.html

Affiliations

Universiti Putra Malaysia, Faculty of Science
Universiti Putra Malaysia, Faculty of Science
Universiti Putra Malaysia, Faculty of Biotechnology and Biomolecular Sciences
Universiti Putra Malaysia, Faculty of Biotechnology and Biomolecular Sciences
Universiti Putra Malaysia, Faculty of Biotechnology and Biomolecular Sciences
Universiti Putra Malaysia, Faculty of Science
Universiti Putra Malaysia, Faculty of Biotechnology and Biomolecular Sciences

Abstract

High performance enzymatic synthesis of oleyl oleate, a liquid wax ester was carried out by lipase-catalysed esterification of oleic acid and oleyl alcohol. Various reaction parameters were optimised to obtain high yield of oleyl oleate. The optimum condition to produce oleyl oleate was reaction time; 5 min, organic solvents of log P ≥ 3.5, temperature; 40-50ºC, amount of enzyme; 0.2-0.4 g and molar ratio of oleyl alcohol to oleic acid; 2:1. The operational stability of enzyme was maintained at >90% yield up to 9 cycles. Analysis of the yield of the product showed that at optimum conditions, >95% liquid wax esters were produced.

Item Type:Journal
Additional Information:This project was financed by a grant from IRPA Project, No.01-02-04-0000-PR, Malaysia.
Keywords:Oleyl oleate, immobilised lipase, esterification, liquid wax ester.
Subjects:S Agriculture
Q Science
ID Code:1893

AKOH, C.C.; COPPER, C. and NWOSU, C.V. Lipase G-catalyzed synthesis of monoglycerides in organic solvent and analysis by HPLC. Journal of the American Oil Chemists' Society, 1992, vol. 69, no. 9, p. 257-260.

ARACIL, J.; GARCIA, T. and MARTINEZ, M. Enzymatic synthesis of an analogue of jojoba oil: Optimisation by statistical analysis. Enzyme and Microbial Technology, 1993, vol. 15, no. 7, p. 607-611.

AWANG, Roila; BASRI, Mahiran; AHMAD, Salmiah and SALLEH, Abu Bakar. Enzyme-catalyzed synthesis and characterization of octyl dihydroxystearate from palm-based dihydroxystearic acid. Journal of Oleo Science, 2003, vol. 52, no. 1, p. 7-14.

BLOOMER, S.; ADLERCREUTZ, P. and MATTIASSON, B. Facile synthesis of fatty acid esters in high yields. Enzyme and Microbial Technology, July 1992, vol. 14, no. 7, p. 546-552.

BOURG-GARROS, S.; RAZAFINDRAMBOA, N. and PAVIA, A. A. Optimisation of lipase-catalyzed synthesis of (z)-3-hexen-1-yl acetate by direct esterification in hexane and solvent-free medium. Enzyme and Microbial Technology, March 1998, vol. 22, no. 4, p. 240-245.

CARTA, Giorgio; GAINER, John L. and BENTON, Alan H. Enzymatic synthesis of esters using an immobilised lipase. Biotechnology and Bioengineering, 1991, vol. 37, no. 11, p. 1004-1009.

CLAON, P.A. and AKOH, C.C. Enzymatic synthesis of geranyl acetate in n-hexane with Candida antartica lipase. Journal of the American Oil Chemists' Society, 1994, vol. 71, no. 11, p. 1177-1182.

CHEN, H. P.; HSIOU, K. F. and WANG, K. T. Regioselectivity enhancement by partial purification of lipase from Aspergillus niger. Biotechnology Letters, 1995, vol. 17, no. 3, p. 305-308.

DE, B.K.; BHATTACHRYYA, D.K. and BANDHU, C. Enzymatic synthesis of fatty alcohol esters by alcoholysis. Journal of the American Oil Chemists' Society, April 1999, vol. 76, no. 4, p. 451-453.

DECAGNY, B.S.; JAN, S.; VUILLEMARD, J.C.; SARAZIN, C.; SEGUIN, J.P.; GOSSELIN, C.; BARBOTIN, J.N.; and ERGAN, F. Synthesis of wax ester through triolein alcoholysis: Choice of the lipase and study of the mechanism. Enzyme and Microbial Technology, May 1998,vol. 22, no. 7, p. 578-582.

ERBELDINGER, Markus; NI, Xiongwei and HALLING, Peter J. Enzymatic synthesis with mainly undissolved substrates at very high concentrations. Enzyme and Microbial Technology, July 1998, vol. 23, no. 1-2, p. 141-148.

FACIOLI, Nara Lucia and BARRERA-ARELLANO, Daniel. Optimisation of enzymatic esterification of soybean oil deoderiser distillate. Journal of the Science of Food and Agriculture, 2001,vol. 81, no. 12, p. 1193-1198.

GILLIES, B.; YAMAZAKI, H. and ARMSTRONG, D. W. Production of flavour esters by immobilised lipase. Biotechnology Letters, 1987, vol. 9, p. 709-719.

GOMA-DONCESCU, N. and LEGOY, M. D. An original transesterification route for fatty ester production from vegetable oils in a solvent-free system. Journal of the American Oil Chemists' Society, 1997, vol. 74, no. 9, p. 1137-1143.

HARI KRISHNA, S.; MANOHAR, B.; DIVAKAR, S. and KARANTH, N.G. Lipase-catalyzed synthesis of isoamyl butyrate: optimisation by response surface methodology. Journal of the American Oil Chemists' Society, December 1999, vol. 76, p. 1483-1488.

HARI KRISHNA, S.; MANOHAR, B.; DIVAKAR, S.; PRAPULLA, S.G. and KARANTH, N.G. Optimisation of isoamyl acetate production by using immobilised lipase from Mucor meihei by response surface methodology. Enzyme and Microbial Technology, February 2000, vol. 26, no. 2-4, p. 131-136.

HARI KRISHNA, S.; SATTUR, A. P. and KARANTH, N.G. Lipase- atalyzed synthesis of isoamyl isobutyrate-optimisation using a central composite rotatable design. Process Biochemistry, 2001, vol. 37, no. 1, p. 9-16.

KANASAWUD, Pawinee; PHUTRAKUL, Suree; BLOOMER, Scott; ADLERCEUTZ, Patrick and MATTIASSON, Bo. Triglyceride interesterification by lipases 3. Alcoholysis of pure triglycerides. Enzyme and Microbial Technology, December 1992, vol. 14, no. 12, p. 959-965.

KLIBANOV, Alexander M. Why are enzymes less active in organic solvents than in water? Trends Biotechnology, March 1997, vol. 15, no. 3, p. 97-101.

KUAN, Ju Liu; ALHINDRA, Nag and SHAW, Jei-Fu. Lipase-catalyzed synthesis of fatty acid diethanolamides. Journal of Agriculture and Food Chemistry, November 2001, vol. 49, no. 12, p. 5761-5764.

LANGRAND, G.; TRANTAPHYLIDES, C. and BARATTI, J. Lipase-catalyzed formation of flavor esters. Biotechnology Letters, 1988, vol. 10, no. 8, p. 549-554.

LIU, K. J. and SHAW, J. F. Synthesis of propylene glycol monoesters of docosahexaenoic acid and eicosapentaenoic acid by lipase-catalyzed esterification in organic solvents. Journal of the American Oil Chemists' Society, 1995, vol. 72, no. 11, p. 1271-1274.

LOZANO, P.; VILLORA, G.; GOMEZ, D.; GAYO, A. B.; SANCHEZ-CONESA, J. A.; RUBIO, M. and IBORRA, J.L. Membrane reactor with immobilised Candica antartica lipase B for ester synthesis in supercritical carbon dioxide. Journal of Supercritical Fluids, April 2004, vol. 29, no. 1-2, p. 121-128.

LOZANO, P.; DE DIEGO, Teresa; CARRIE, Daniel; VAULTIER, Michel and IBORRA, José. Enzymatic ester synthesis in ionic liquids. Journal of Molecular Catalysis B: Enzymatic, January 2003, vol. 21, no. 1-2, p. 9-13.

MCGILVERY, R.W. and GOLDSTEIN, G.W. Rates of enzymatic reaction, In: Biochemistry: A Functional Approach. 3rd Edition, Philadelphia, London, Toronto Mexico City and Tokyo; W. B. Saunders Company, 1983, p. 296-307.

MUKERJEE, Kumar D. and KIEWITT, Irmgard. Preparation of esters resembling natural waxes by lipase-catalyzed reactions. Journal of Agriculture and Food Chemistry, 1988, vol. 36, no. 6, p. 1333-1336.

PETER, T.R and ROBERT, B. Beeswax through the ages. Personal care, October 2001, vol. 10, p. 27-31.

PRAPULLA, S.G.; KARANTH, N.G.; ENGEL, K.H. and TRESSEL, R. Production of 6-pentyl-a-pyrone by Trichoderma viridian. Journal of Flavor Fragrance, 1992, vol. 7, p. 231-234.

RAMAMURTHY, S. and MCCURDY, A.R. Lipase-catalyzed esterification of oleic acid and methanol in hexane - A kinetic study. Journal of the American Oil Chemists' Society, 1994,vol. 71, no. 9, p. 927.

SELLAPAN, Subramani and AKOH, Casimir C. Enzymatic acidolysis of tristearin with lauric and oleic acid to produce coating lipids. Journal of the American Oil Chemists' Society, November 2000, vol. 77, no. 11, p. 1127-1133.

TORRES, Carlos and Otero, Cristina. Part III. Direct enzymatic esterification of lactic acid with fatty acids. Enzyme and Microbial Technology, 2001, vol. 29, no. 1, p. 3-12.

VIRTO, C. and ADLERCREUZ, P. Lysophophatidylcholine synthesis with Candida antartica lipase.Enzyme and Microbial Technology, 2000, vol. 26, no. 8, p. 630-635.

WILLING, A. Oleochemical esters-environmentally compatible raw materials for oils and lubricants from renewable resources. European Journal of Lipid Science and Technology, 1996, vol. 101, p. 192-197.

YEE, Lisa N.; AKOH, Casimir C. and PHILIPS, S.G. Lipase PS-catalyzed transesterification of citronellyl butyrate and geranyl caproate; effect of reaction parameters. Journal of the American Oil Chemists' Society, March 1997,vol. 74, p. 255-260.

ZHANG, Hong; XU, Xuebing; MU, Huiling; NILSSON, Jorgen; ADLER-NISSEN, Jens and HOY, Carl-Erik. Lipozyme IM catalysed interesterification for the production of margarine fats in a 1 Kg scale stirred tank reactor. European Journal of Lipid Science and Technology, 2000, vol. 102, no. 6, p. 411-418.

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