Author, Subjects, Keywords

Cited Author

 
 
   » By Author or Editor
 » Browse Author by Alphabet
 » By Journal
 » By Subjects
 » Malaysian Journals
 » By Type
 » By Year
 » By Latest Additions
 
 
   » By Author
 » Top 20 Authors
 » Top 20 Article
 » Top Journal Cited
 » Top Article Cited
 » Journal Citation Statistics
 » Usage Since Sept 2007


 
 
 

Login | Create Account

Ultrasonic study of the self-association of aniline in ethanol-cyclohexane mixtures

Thiyagarajan, R., and Mohamad Suhaimi Jaafar, and Palaniappan, L. , (2007) Ultrasonic study of the self-association of aniline in ethanol-cyclohexane mixtures. Journal of Physical Science, 18 (2). pp. 81-88.

[img]
Preview
PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
136Kb

Official URL: http://www.usm.my/jps/18-2-07/Article%2018-2-6.pdf

Affiliations

Annamalai University, India. Dept. of Physics
Universiti Sains Malaysia. School of Physics
Universiti Sains Malaysia. School of Physics

Abstract

Sound velocity (U), density (ρ) and viscosity (η) values have been measured at 303 K in the ternary system of aniline+methanol+cyclohexane. From these data, acoustical parameters such as adiabatic compressibility (β), free length (Lf), free volume(Vf) and internal pressure(πi) have been estimated using the standard relations. The results are interpreted in terms of molecular interaction between the components of the mixtures. Observed excess value in the mixture indicates the existence of dipole-induced dipole and dipole-dipole interactions in the system.

Item Type:Journal
Keywords:ultrasonic velocity, ternary system, molecular interactions
Subjects:Q Science, Computer Science
ID Code:5356

1. Venkatesu, P., Sekhar, G.C. & Rao, M.V.P (2006). Ultrasonic studies of N,N-dimethylformamide cyclohexanone 1-alkanols at 303.15 K. Phys. & Chem. of Liquids, 44, 287–291.

2. Awasthi, A. & Shukla, J.P. (2003). Ultrasonic and IR study of intermolecular association through hydrogen bonding in ternary liquid mixtures. Ultrasonics, 41(6), 477–486.

3. Muhuri, P.K., Das, B. & Hazra, D.K. (1996). Apparent molar volumes and apparent molar compressibilities of some symmetriced tetraalkylammonium bromites in 1,2–dimethoxyethane. Indian J. Chem., 35A, 287–291.

4. Jayakumar, S., Ram, S.G., Karunanidhi, N. & Kannappan, V. (2001). Polarisability and acoustical studies of electrolytic solutions. J. Pure. Appl. Ultrason., 23, 31–35.

5. Pal, A., Sharma, S. & Kumar, A. (2000). Speeds sound and isentropic compressibilities of mixtures containing polyesters and ethyl acetate at temperature 298.15 K. Indian J. Pure Appl. Phys., 38, 174–179.

6. Nayakulu, S.V.R., Venkateswar, S., Reddy, C.S. & Reddy, D.L. (2006). Ultrasonic and sonochemical reaction studies of o-cresols in different solvent mixtures. Phys. Chem. of liquids, 44, 269–273.

7. Arul, G. & Palaniappan, L. (2000). Estimation of sound velocity in ternary liquid mixture of 2-propanal in cyclohexane with toluene. J. Acoust. Soc. India, 28,393–395.

8. Nikam, P.S., Hasan, M. & Pathak, R.B. (1996). Densities and speeds of sound for aniline+aliphatic alcohols (C1–C4) at different temperatures. J. Pure Appl. Ultrason.,18,19–25.

9. Arun Bahl, B.S. & Bhat, S. (2005). Advanced organic chemistry, 17th ed. New Delhi: S. Chand & Co Ltd., 231–245.

10. Lide, D.R. (2002–2003). CRC Handbook of chemistry and physics, 83rd ed. New York: CRC Press.

11. Arul, G. & Palaniappan, L. (2001). Molecular interaction studies in the ternary mixture of cyclohexane+toluene+2-propanol. Indian J. Pure Appl. Phys., 39, 561–564.

12. Arul, G. & Palaniappan, L. (2005). Ultrasonic study of 1-butanol in pyridine with benzene. Indian J. Pure Appl. Phys., 43, 755–758.

13. Peters, E.I. (1982). Introduction to chemical principles (Ch.14), 3rd ed. Philadelphia: CBS College Publishing, 324–326.

14. Eliel, E.L. (1985). Stereochemistry of carbon compounds, 9th ed. New Delhi: Tata McGraw Hill, 95–97.

15. Dean, J.A. (1987). Lange’s Handbook of chemistry, 13th ed. New York: McGraw Hill Int.,186.

16. Palaniappan, L. (2001). Ultrasonic study of 2-butanol in cyclohexane with toluene. Indian J. Phys.,75B(6),515–518.

17. Palaniappan, L. (2002). Thermo acoustical studies of some iso-alcohols in cyclohexane with toluene. Indian J. Pure Appl. Phys., 40, 828–830.

18. Palaniappan, L., Devadoss, D. & Thairiyaraja, M. (2003). Molecular interactions studies in the ternary mixtures of 1-hexanol+acetonitrile+ cyclohexane. Indian J. Phys., 77 B(6), 679–682.

19. Deshpande, D.D & Bhatgadde, L.G. (1968). Sound velocities, adiabatic compressibilities and free volumes in aniline solutions. J. Phys. Chem., 72, 261–266.

20. Fort, R.J. & Moore, W.R. (1965). Adiabatic compressibilities of binary liquid mixtures, evaluation of excess isentropic compressibilities and viscosities of n-but oxygethenols with water at 298.15 K. Trans. Faraday Soc., 61, 2102–2106.

21. Ali, A. & Nain, A.K. (2002). Ultrasonic study of molecular interaction in binary liquid mixtures at 30°C. PRAMANA, 58, 695–701.

22. Sundharam, N. & Palaniappan, L. (2005). Molecular interaction studies in the ternary mixtures of methanol+benzene+cyclohexane. Indian J. Phys.,79(10),1173–1178.

Repository Staff Only: item control page
 
 
 
 
 
 
© Copyright 2007 MyAIS Faculty of Computer Science and Information Technology, University of Malaya – All Rights Reserved. Malaysian Abstracting and Indexing System is powered by EPrints 3 which is developed by the School of Electronics and Computer Science at the University of Southampton. More information and software credits.